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11.
Andrea Desii Federica Chiellini Celia Duce Lisa Ghezzi Susanna Monti Maria R. Tiné Roberto Solaro 《Journal of polymer science. Part A, Polymer chemistry》2010,48(4):889-897
We investigated the self‐aggregation of 12 short ionic oligopeptides constituted by 4–7 amino acid residues to establish useful structure–property relationships that might be exploited in the biomedical field by using the concept of molecular Lego. We show that the critical aggregation concentration (CAC) of tetrapeptides decreases with increasing hydrophobicity of neutral residues. Additionally, the dependence of the CAC of isomeric oligopeptides on the distribution of amino acid residues confirms the high tendency to self‐organization of molecules with alternating ionic and neutral residues. Indeed, atomic force microscopy (AFM) images recorded on oligopeptide solutions above the CAC show the presence of either fibrillar or spherical aggregates depending on oligopeptide structure and concentration, steric hindrance, solution pH, and time. The potential of the investigated oligopeptides in tissue engineering applications is supported by their in vitro cytocompatibility. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 889–897, 2010 相似文献
12.
This paper considers some properties of a class of transformed Markov processes. The analogy with Whittle's relaxed Markov process is pointed out. Some applications of the transformed Markov processes to queueing networks are described 相似文献
13.
14.
We present a numerical method for reconstructing the coefficient in a wave equation from a single measurement of partial Dirichlet boundary data. The original inverse problem is converted to a nonlinear integral differential equation, which is solved by an iterative method. At each iteration, one linear second‐order elliptic problem is solved to update the reconstruction of the coefficient, then the reconstructed coefficient is used to solve the forward problem to obtain the new data for the next iteration. The initial guess of the iterative method is provided by an approximate model. This model extends the approximate globally convergent method proposed by Beilina and Klibanov, which has been well developed for the determination of the coefficient in a special wave equation. Numerical experiments are presented to demonstrate the stability and robustness of the proposed method with noisy data.© 2014 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 289–307, 2015 相似文献
15.
A Solution‐Processed Air‐Stable Perylene Diimide Derivative for N‐type Organic Thin Film Transistors
Heng‐Wen Ting Szu‐Ying Chen Tin‐Chun Huang Prof. Jeng‐Hua Wei Prof. Tri‐Rung Yew 《Chemphyschem》2011,12(4):871-877
For future all‐soluble organic thin film transistor (OTFT) applications, a new soluble n‐type air‐stable perylene diimide derivative semiconductor material with (trifluoromethyl)benzyl groups (TC–PDI–F) is synthesized. The film is formed by spin‐coating in air and optimized for OTFT fabrications. The transistor characteristics and air‐stability of the TC–PDI–F OTFTs is measured to investigate the feasibility of using solution‐processed TC–PDI–F for future OTFT applications. For all‐solution OTFT process applications, the transistor characteristics are demonstrated by using TC–PDI–F as an n‐type semiconductor material and liquid‐phase‐deposited SiO2 (LPD–SiO2) as a gate dielectric material. All processes (except material synthesis and electrode deposition) and electrical measurements are conducted in air. 相似文献
16.
G.A. Anzelon I. Šlaus S.Y. Tin W.T.H. Van Oers R.M. Eisberg M. Makino C.N. Waddell M.B. Epstein 《Nuclear Physics A》1975,255(2):250-266
Proton-α bremsstrahlung cross sections have been measured at 45 MeV for θp = 91°, θα = 30° and θp = 70°, θα = 39°; at 40 MeV for θp = 92°, θα = 29°; and at 22 MeV for θp = 70°, θα = 30°. Calculations for these cross sections have been made using the Feshbach-Yennie model following the methods of Green and Prodon including p-α partial waves up to L = 4. These potential-independent calculations have only the proton-α elastic-scattering phase shifts as input. Good agreement with the experimental cross sectios has been obtained. 相似文献
17.
Phosphorescence excitation and emission spectral peaks, lifetimes, working curves and limits of detection of 22 organic compounds of pharmacological importance in rigid (77°K) ethanolic solution are given. Ethanol can be easily prepared in a high degree of purity, and most drugs are much more soluble in ethanol than in most solvents previously used for phosphorimetric studies. The possible application of phosphorimetry to the trace analysis of drugs in biological fluids is discussed. 相似文献
18.
Biver T Lombardi D Secco F Tiné MR Venturini M Bencini A Bianchi A Valtancoli B 《Dalton transactions (Cambridge, England : 2003)》2006,(12):1524-1533
The macrocyclic polyamine 2,5,8,11,14-pentaaza[15]-[15](2,9)[1,10]phenanthrolinophane (neotetren) is studied in its ability to coordinate Cu(ii) even at very low pH values and to interact, as a metal complex, with DNA. The kinetics and equilibria for 1 : 1 and 2 : 1 metal-ligand complexes formation are studied by the stopped-flow method and UV spectrophotometry. Differently protonated complexes are formed, with rate constants much lower than that of water exchange at copper(II) and other Cu(II)/amine systems, this behaviour being ascribed to ring effects and intra-molecular hydrogen bonds. Concerning the DNA/copper(II)-neotetren complexes interaction, analysis of data suggests an intercalative mode of binding. The kinetic results for both DNA/CuL and DNA/Cu(2)L systems agree with the sequence D + S <-->D,S <-->DS where the metal complexes (D) react with the DNA sites (S) leading to fast formation of an externally bound form (D,S) which is converted into an intercalated complex (DS). A very slow process is also detected and ascribed to a conformational change in the polynucleotide secondary structure where the metal centre plays a crucial role. Chromatographic experiments demonstrate that both the investigated Cu(II)/L complexes are able to cleave DNA, but only in the presence of hydrogen peroxide. 相似文献
19.
Bernazzani L Duce C Micheli A Mollica V Sperduti A Starita A Tiné MR 《Journal of chemical information and modeling》2006,46(5):2030-2042
In this paper, we report on the potential of a recently developed neural network for structures applied to the prediction of physical chemical properties of compounds. The proposed recursive neural network (RecNN) model is able to directly take as input a structured representation of the molecule and to model a direct and adaptive relationship between the molecular structure and target property. Therefore, it combines in a learning system the flexibility and general advantages of a neural network model with the representational power of a structured domain. As a result, a completely new approach to quantitative structure-activity relationship/quantitative structure-property relationship (QSPR/QSAR) analysis is obtained. An original representation of the molecular structures has been developed accounting for both the occurrence of specific atoms/groups and the topological relationships among them. Gibbs free energy of solvation in water, Delta(solv)G degrees , has been chosen as a benchmark for the model. The different approaches proposed in the literature for the prediction of this property have been reconsidered from a general perspective. The advantages of RecNN as a suitable tool for the automatization of fundamental parts of the QSPR/QSAR analysis have been highlighted. The RecNN model has been applied to the analysis of the Delta(solv)G degrees in water of 138 monofunctional acyclic organic compounds and tested on an external data set of 33 compounds. As a result of the statistical analysis, we obtained, for the predictive accuracy estimated on the test set, correlation coefficient R = 0.9985, standard deviation S = 0.68 kJ mol(-1), and mean absolute error MAE = 0.46 kJ mol(-1). The inherent ability of RecNN to abstract chemical knowledge through the adaptive learning process has been investigated by principal components analysis of the internal representations computed by the network. It has been found that the model recognizes the chemical compounds on the basis of a nontrivial combination of their chemical structure and target property. 相似文献
20.
Jarinee Kiang-ia Rahut Taeudomkul Pongthep Prajongtat Padetha Tin Apichart Pattanaporkratana Nattaporn Chattham 《Molecules (Basel, Switzerland)》2021,26(14)
Continuous rotation of a cholesteric droplet under the heat gradient was observed by Lehmann in 1900. This phenomenon, the so-called Lehmann effect, consists of unidirectional rotation around the heat flux axis. We investigate this gradient heat effect using infrared laser optical tweezers. By applying single trap linearly polarized optical tweezers onto a radial achiral nematic liquid crystal droplet, trapping of the droplet was performed. However, under a linearly polarized optical trap, instead of stable trapping of the droplet with slightly deformed molecular directors along with a radial hedgehog defect, anomalous continuous rotation of the droplet was observed. Under low power laser trapping, the droplet appeared to rotate clockwise. By continuously increasing the laser power, a stable trap was observed, followed by reverse directional rotation in a higher intensity laser trap. Optical levitation of the droplet in the laser beam caused the heat gradient, and a breaking of the symmetry of the achiral nematic droplet. These two effects together led to the rotation of the droplet under linearly polarized laser trapping, with the sense of rotation depending on laser power. 相似文献